When you're designing a new app, you can figure out how the app will look and work by creating mockups of each screen. This can be as simple as drawing sketches on paper, or you can use a number of software tools to create a digital mockup.
Hardcopy
iPhone Stencil Kit - a stainless steel stencil for drawing iPhone interface elements.
iPhone & iPad Sketch Books from App Mockup Tools
Digital
iOS App Icon Template for Photoshop
iPhone GUI Elements for Photoshop by Teehan+Lax. They also have an iPad version.
MockApp offers templates for Keynote or PowerPoint
Both
idev101's App Design Templates for Photoshop and print
Apps
AppCooker is an app for designing app mockups.
Pop App lets you take pictures of your app sketches and create a working demo on your iPhone.
Graphics
Here are some Buttons & Icons and Graphics Apps you can use when designing your app.
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